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AAT Bioquest

How do I find the oxidation number?

Posted August 27, 2024


Answer

To find the oxidation number, one has to use the oxidation number rules. One of the rules is that oxygen has an oxidation number of -2 in most compounds. Alkali metals always have an oxidation number of +1 in their compounds and alkaline earth metals always have an oxidation number of +2. In a neutral compound, the sum of the oxidation numbers of all atoms must be zero. In a polyatomic ion, the sum of the oxidation numbers must equal the charge of the ion. As an example, for sulfur dioxide (SO₂), assign oxidation numbers based on the rule that oxygen generally has an oxidation number of -2. Thus since there are 2 oxygens, it would give a sum of -4, and since the sum of the oxidation numbers of all atoms must be zero (for neutral compounds like this), the oxidation number is 4. 

Additional resources

Assigning Oxidation Numbers

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